Synthesis and Characterization of Co(II), Ni(II), Cu(II) and Zn(II) Complexes with Schiff Bases Derived from 3-Substituted-4-Amino-5-Mercapto-1,2,4-Triazoles and Ethylvanillin

Authors

  • Kiran Singh Department of Chemistry, Kurukshetra University, Kurukshetra-136119, India
  • Rakesh Kumar Department of Chemistry, Kurukshetra University, Kurukshetra-136119, Haryana, India
  • Parveen Kumar Department of Chemistry, Kurukshetra University, Kurukshetra-136119, Haryana, India

DOI:

https://doi.org/10.37591/jomcct.v4i2.2019

Keywords:

Schiff's Base, polymer, electronic spectra

Abstract

The synthesis and structural characterization of two novel compounds, 4-(3-ethoxy-4-hydroxybenzylideneamino)-3-methyl-5-mercapto-s-triazole and 3-ethyl-4-(3-ethoxy-4-hydroxybenzylideneamino)-5-mercapto-s-triazole and their Co(II), Ni(II), Cu(II), Zn(II) complexes in 1:1 and 1:2 molar ratio have been described with the help of different techniques like IR, 1H-NMR, magnetic moment, electronic spectra, thermal and XRD studies. The Schiff bases are coordinated to metal ion through S and N. Octahedral geometry has been proposed around Co(II), Ni(II) and Zn(II) metal ions and in case of Cu(II) the square planar geometry is expected.

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Published

2019-05-03

Issue

Vol. 4 No. 2 (2013)

Section

Articles

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