Optical Absorption and Electronic Properties of 4-Amino- antipyrine Schiff’s Bases: A Combined Experimental and DFT Study

Authors

  • Chetty Prabhakar Department of Chemistry, National Institute of Technology, Kurukshetra, Haryana, India
  • A. Aruna Department of Chemistry, Raja Bahadur Venkata Rama Reddy Women’s College, Hyderabad, Telangana, India
  • Anuj Tripathi Department of Chemistry, National Institute of Technology, Kurukshetra, Haryana, India
  • B. Anupama Department of Chemistry, Raja Bahadur Venkata Rama Reddy Women’s College, Hyderabad, Telangana, India

DOI:

https://doi.org/10.37591/jomcct.v8i1.1898

Keywords:

Amino- antipyrine based Schiff's bases, optical absorption of Schiff's base

Abstract

The Schiff base compounds (A1–A9) have been synthesized and characterized by elemental analysis, FT-IR, UV-Vis, mass spectrometry, 1H-NMR and 13C-NMR. Electronic absorption spectra of A1–A9 are studied in various solvents with different polarity like hexane, chloroform, methanol and dimethyl sulfoxide. To support and better understanding of experimental results, density functional theory (DFT), time dependent density functional theory (TDDFT) calculations has been carried out for these molecules and are in good agreement with the experimental values

Downloads

Published

2019-04-23

Issue

Vol. 8 No. 1 (2017)

Section

Articles

License

Declaration and Copyright Transfer Form

(to be completed by authors)

I/ We, the undersigned author(s) of the submitted manuscript, hereby declare, that the above manuscript which is submitted for publication in the STM Journals(s), is not published already in part or whole (except in the form of abstract) in any journal or magazine for private or public circulation, and, is not under consideration of publication elsewhere.

  • I/We will not withdraw the manuscript after 1 week of submission as I have read the Author Guidelines and will adhere to the guidelines.
  • I/We Author(s ) have niether given nor will give this manuscript elsewhere for publishing after submitting in STM Journal(s).
  • I/ We have read the original version of the manuscript and am/ are responsible for the thought contents embodied in it. The work dealt in the manuscript is my/ our own, and my/ our individual contribution to this work is significant enough to qualify for authorship.
  •  I/We also agree to the authorship of the article in the following order:

Author’s name                                    

 

1. ________________

2. ________________

3. ________________

4. ________________

 

We  Author(s) tick this box and would request you to consider it as our signature as we agree to the terms of this Copyright Notice, which will apply to this submission if and when it is published by this journal.