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Copper(II) Catalyzed Oxidation of Hydrazine Hydrate by Hexacyanoferrate(III)
Abstract
The kinetics of Cu(II) catalyzed oxidation of hydrazine by hexacyanoferrate(III) is studied in acid medium. The stoichiometry of the reaction is 1:1. The first order condition [N2H5] > [Fe(CN)63−] is maintained. The order of the reaction is unity with respect to Fe(CN)63−, fractional orders with respect to hydrazine and copper. The reaction is independent of variation of sulphuric acid and ionic strength. A suitable mechanism is proposed for the reaction
Keywords
Hexacyanoferrate(III), oxidation, hydrazine hydrate
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PDFDOI: https://doi.org/10.37591/jomcct.v3i1-3.2028
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